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16.

For  the elementary reaction M→ N,  the rate of disappearance of M increases by  a factor of 8 upon doubling   the concentration of M. The order of the reaction with respect to M is


A) 4

B) 3

C) 2

D) 1



17.

For the process, $H_{2}O (l)\rightarrow H_{2}O(g)$ at   T= 100° C and 1 atmosphere  pressure, the correct choice is 


A) $\triangle S_{system}$ > 0 and $\triangle S_{surrounding}$ > 0

B) $\triangle S_{system}$ > 0 and $\triangle S_{surrounding}$ < 0

C) $\triangle S_{system}$ < 0 and $\triangle S_{surrounding}$ > 0

D) $\triangle S_{system}$ < 0 and $\triangle S_{surrounding}$ < 0



18.

Assuming 2s-2p mixing is not operative, the paramagnetic  species among the following is 


A) $Be_{2}$

B) $B_{2}$

C) $C_{2}$

D) $N_{2}$



19.

Consider all possible isomeric ketones including stereoisomers of MW=100, All  these isomers are independently reacted with NaBH4 (Note stereoisomers are also  reacted separately.) The total number of ketones that give a racemic product (s)  is/are


A) 5

B) 6

C) 7

D) 8



20.

Among PbS, CuS,HgS, MnS,Ag2S, NiS,CoS, Bi2S3 and SnS2 the total number of black coloured sulphide is 


A) 7

B) 5

C) 6

D) 4



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